Ignition is a file organizer tool that minimizes the number of CDs required to burn a massive number of files.
Ignition features the ability to create ISO images (requires CopyToDVD) and automatically create folders for each optimized CD. Or it can also create a TXT file containing the optimized list of each CD's content and the ability to put a bunch of files on every media (autorun, codecs, etc.).
The "burn" feature requires VSO's CopyToCD to work. It includes support for 650,700 Mb CDs, HD Burn CDs, and DVDs (even Dual Layer DVDs)